NANOCOSMOS has developed a custom-designed vacuum chamber for the study of gas-phase molecular species through rotational spectroscopy. The innovative breakthrough is the coupling of the chamber to the new NANOCOSMOS millimeter broad band receivers. These receivers are twins of those built for the Yebes 40 meter radio telescope. We call the whole experimental setup as GACELA – Gas Cell for Laboratory Astrophysics.
Our experiments address the characterization of molecules that represent a considerable fraction of all the molecular species detected in the interstellar medium – ISM – but present rotational parameters not precise enough to allow their detection in the ISM. Therefore, we have used GACELA to measure the rotational spectrum of 4 molecular species in the frequency ranges 31.5–50 GHz (Q band) and 72–116.5 GHz (W band) in the laboratory. At the same time, we support these spectroscopic studies with high-level ab initio calculations. Finally, we use the derived experimental rotational parameters to allow the search of these molecular species in astrophysical environments.
We have complemented the GACELA experiments with other techniques like Fourier transform microwave (FTMW) spectroscopy at UVA (11 molecular compounds), absorption spectroscopy (2 molecular compounds) and cryogenic trapping machine experiments (7 protonated molecular species).
Below, we show a summary table on the performed experimental characterizations and techniques. We also include the Nanocosmos publication when clicking on the compound. For Polycyclic aromatic hydrocarbons (PAHs), proceed far below after the table (new page).
Methyl silane (CH3SiH3) and silyl cyanide (SiH3CN, first time in Space)
We propose a formation mechanism through catalytic reactions on the surface of dust grains by hydrogenation of silicon-carbon species in the inner dust formation zone
Formation of SiC dust in C-rich AGBs
SiC2, CS, SiO and SiS gas-phase precursors of dust
Decline in the abundances of these molecular species with increasing density in the envelopes of C-rich AGB stars. Important constraints for Stardust experiments on SiC dust formation.
Formation of dust in O-rich AGBs
SiO and SO gas-phase precursors of dust
Decline in the abundances of these molecular species with increasing density in the envelopes of O-rich AGB stars
Discovery of molecular species in the Interstellar Medium
7 molecules, including one protonated form and isotopologs (2 of them, first time in Space)
See dedicated descriptions below (under construction)
Major NANOCOSMOS highlights in “ALMA/IRAM observations” (see dedicated descriptions below)
NANOCOSMOS has performed several key observations of the circumnuclear envelopes -CSEs- of AGB stars with the IRAM 30m radio telescope and the ALMA interferometer. These observations are mandatory to foster the study of the gas-phase precursors of dust in these envelopes. We have made fruitful efforts in the study of the Si-C chemistry in these objects.
NANOCOSMOS has discovered methyl silane, CH3SiH3 and silyl cyanide (SiH3CN) in the envelope of the C-rich AGB star IRC +10216. We suggest that both are formed in the inner zones of the circumstellar envelope through catalytic reactions on the surface of dust grains by hydrogenation of silicon-carbon species.
We have also performed two molecular surveys with the IRAM facility, one to study the envelopes of 25 C-rich AGB stars to search for emission lines of SiC2, SiC, Si2C, CS, SiO and SiS and another one with a sample of 30 O-rich AGB stars to investigate the potential role of SiO, CS, SiS, SO, and SO2 in the formation of dust in these environments.
Our results show strong evidences that the observed decline in the molecular abundances of these species with increasing density in the envelopes are due to their incorporation to the solid phase. Furthermore, we establish that SiC2, CS, SiO and SiS (tentatively) are very likely gas-precursors of SiC dust in C-rich envelopes of AGB stars and SiO and SO (tentatively) in O-rich AGB stars.
Finally, the team has detected 7 molecules in the Interstellar Medium, some of them of key importance to constrain chemical models. These are the c-C3D isotopologs, the metastable and polar isomer isocyanogen (CNCN), the isocyanate radical NCO, the thioformyl radical (HCS) and its metastable isomer HSC, all of them in the dark cold cloud core L483, which contains a low-mass protostar. We have also detected ethyl formate (CH3CH2OCOH) and NS+ in the young protostellar system Barnard 1b with ALMA and IRAM respectively.
Major emission arises at 50 AU or less from the star in the dust formation zone. Constraints on chemical models
Distribution of molecular emission in IRC+10216
Part of the emission arises in the inner dust formation zone contrary to previous findings. Constraints on chemical models
Detection of molecular emission in R Leo
CO2 Infrared fluorescence
More systematic study of the CO2 emission in O-rich stars to understand how CO2 forms
Major NANOCOSMOS highlights in “High spectral resolution IR observations” (see dedicated descriptions below)
High spectral resolution infrared observations of circumstellar envelopes – CSEs – in AGB stars are essential to study important molecular species with no permanent dipole moment (e.g. H2, O2, CO2, SiH4, C2H4). This lack makes them undetectable in the millimeter range due to the absence of rotational transitions. Hence, the best possible observation of these molecules is through its vibration–rotation lines in the mid infrared range.
These observations are vital to study the amount of ejected matter in the pulsation phase and determine the chemical interactions between the ejected molecules in the CSEs. These studies help improve the underlying assumptions of currently available chemical models.
Therefore, we observed the carbon-rich star IRC+10216 with the Texas Echelon-cross-Echelle Spectrograph (TEXES) on the 3 m Infrared Telescope Facility (IRTF). We carried out observations of the oxygen rich star R Leo with the Stratospheric Observatory for Infrared Astronomy (SOFIA) with the high spectral resolution Echelon-cross-Echelle Spectrograph (EXES). Finally, we used both SOFIA/EXES and IRTF/TEXES to observe the carbon rich semi-regular star Y CVn.
Our IR observations have led to the discovery of diacetylene(C4H2) in the envelope of IRC+10216 with the major emission arising in the dust formation zone at less than 50 AU from the center of the star. Ethylene (C2H4) shows emission from the inner dust formation zone in IRC+10216 contrary to previous findings. These studies pose further constraints on current chemical models.
Summary of oustanding results with the NANOCOSMOS high-resolution infrared observations of CSEs in AGB stars
C4H2 (24 absorption features in the range 8.0 to 8.1 μm) – First detection in IRC+10216
The major emission of C4H2 arises in the dust formation zone at radii lower than 20 stellar radii (50 Astronomical Units) from the center of IRC+10216
Our photochemical models underestimate the observed C4H2 abundance. This finding could imply that the molecules in the envelope are photodissociated in shells closer to the star than is commonly assumed
C2H4 (80 ro-vibrational features in absorption) – Part of the emission arises in the inner dust formation zone contrary to previous findings
Part of the emission of ethylene arises in the dust formation zone at radii between 14 and 28 stellar radii from the center of IRC+10216, with no evidence of C2H4 closer to the star. Previous findings supposed all C2H4 arises in the far outer envelopes.
Our photochemical models underestimate the observed C2H4 terminal abundance by a factor of 4. We estimate that a fraction of the ethylene gas-phase could condense onto the dust grains around 20 stellar radii. this fact could affect the chemistry evolution of the envelope
The Gas Cell for Laboratory Astrophysics (GACELA) consists of a stainless-steel chamber 1 meter long and a diameter of 60 cm. It is equipped with two teflon windows that allows the study of gases through rotational spectroscopy inside the chamber.
Hence, the team coupled the new NANOCOSMOS millimeter broad band receivers into the setup. These receivers are twins of those built for the Yebes 40 meter radio telescope. A series of vacuum chamber ports allow the injection of gas and liquids to perform plasma generation, ultraviolet photochemistry and optical spectroscopy. GACELA was built at the Segainvex Laboratories located at the Universidad Autónoma de Madrid.
Outstanding publications on our experimetal setup:
GACELA addresses an innovative potential to perform novel experiments on plasma physics, photochemistry and ices. We also address the spectroscopical characterization of a gas injected in the cell. Thus, we performed a first set of experiments in February 2018 with the detection of CH3CN in a few seconds with a very high signal-to-noise ratio (S/N). The whole system was further improved and we have made multiple runs in the full-experimental phase from May 2018.